Another way forward (quite similar to pdeffebach suggestion):
julia> df = DataFrame(month=["202404","202405","202406"], ac_hrs=[2,4,5], crew_hrs=[4,6,7])
3×3 DataFrame
Row │ month ac_hrs crew_hrs
│ String Int64 Int64
─────┼──────────────────────────
1 │ 202404 2 4
2 │ 202405 4 6
3 │ 202406 5 7
julia> coalesce.(leftjoin(DataFrame(month=["2024$(lpad(i,2,'0'))" for i in 1:6]),df;on=:month, order=:left),0)
6×3 DataFrame
Row │ month ac_hrs crew_hrs
│ String Int64 Int64
─────┼──────────────────────────
1 │ 202401 0 0
2 │ 202402 0 0
3 │ 202403 0 0
4 │ 202404 2 4
5 │ 202405 4 6
6 │ 202406 5 7
This is not the exact OP result, but makes it easy to get there and may be enough as it is.