Do you mean this?
julia> df = DataFrame(A=1:4, B=["A", "B", "C", "D"])
4×2 DataFrame
Row │ A B
│ Int64 String
─────┼───────────────
1 │ 1 A
2 │ 2 B
3 │ 3 C
4 │ 4 D
julia> df.b_again = copy(df.B);
julia> df.b_again[2] = "E";
julia> df
4×3 DataFrame
Row │ A B b_again
│ Int64 String String
─────┼────────────────────────
1 │ 1 A A
2 │ 2 B E
3 │ 3 C C
4 │ 4 D D