The simplest way to do it is:
julia> using DataFrames
julia> df = DataFrame(x=1:4, y=2:5)
4×2 DataFrame
Row │ x y
│ Int64 Int64
─────┼──────────────
1 │ 1 2
2 │ 2 3
3 │ 3 4
4 │ 4 5
julia> Tuple.(eachrow(df))
4-element Vector{Tuple{Int64, Int64}}:
(1, 2)
(2, 3)
(3, 4)
(4, 5)
If your data frame has very many rows instead do:
julia> Tuple.(Tables.namedtupleiterator(df))
4-element Vector{Tuple{Int64, Int64}}:
(1, 2)
(2, 3)
(3, 4)
(4, 5)
which is faster for very long tables.