You could use Roots.jl to find zeros of the first derivative of the spline.
Here is a quick example using Newton’s method:
using BSplineKit
using Roots
f(x) = cos(4π * x) * exp(-4x)
xs = 0:0.05:1
S = spline(interpolate(xs, f.(xs), BSplineOrder(6)))
S′ = diff(S, Derivative(1))
S″ = diff(S, Derivative(2))
x₀ = 0.5 # initial guess for Newton method
x = find_zero((S′, S″), x₀, Roots.Newton()) # 0.47547599925831957
S(x) # 0.1422509042378483
S′(x) # -1.5265566588595902e-16